Physics-11 : 12: Kinetic Theory - Flashcards
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What is kinetic theory of gases?
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The theory that explains the behaviour of gases based on the idea that a gas consists of rapidly moving atoms or molecules.
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| # | Question | Answer |
|---|---|---|
| 1 | What is kinetic theory of gases? | The theory that explains the behaviour of gases based on the idea that a gas consists of rapidly moving atoms or molecules. |
| 2 | What is the ideal gas equation? | \( PV = \mu RT \). |
| 3 | What is Boyle's law? | At constant temperature, the pressure of a given mass of gas is inversely proportional to its volume: \( PV = \text{constant} \). |
| 4 | What is the expression for the pressure of an ideal gas according to kinetic theory? | \( P = \frac{1}{3} n m \overline{v^2} \). |
| 5 | What is the average translational kinetic energy of a molecule? | \( \frac{3}{2} k_B T \). |
| 6 | How many translational degrees of freedom does a monatomic gas molecule have? | Three. |
| 7 | What is the molar specific heat at constant volume for a monatomic gas? | \( C_v = \frac{3}{2} R \). |
| 8 | What is the expression for mean free path? | \( l = \frac{1}{\sqrt{2} n \pi d^2} \). |
| 9 | What is the kinetic interpretation of temperature? | The average kinetic energy of a molecule is \( \frac{3}{2} k_B T \). |
| 10 | Three vessels contain neon, chlorine and uranium hexafluoride at the same temperature and pressure. In which case is \( v_{rms} \) the largest? | Neon. |
| 11 | A vessel contains neon and oxygen with partial pressures in the ratio 3:2 (Example 12.4). What is the ratio of the number of molecules of neon to oxygen? | 3:2, since \(P_1/P_2=\mu_1/\mu_2=N_1/N_2\) at the same V and T. |
| 12 | A ball rebounding off a bat moving towards it speeds up (relative to the ground). How does this explain why a gas heats up when compressed by an inward-moving piston? | Each molecule striking the inward-moving piston rebounds faster, just like the ball off the moving bat — so the gas molecules' average speed (and hence temperature) increases. (Example 12.7) |
| 13 | Is the average of a squared quantity, \(\langle v^2 \rangle\), always equal to the square of the average, \((\langle v \rangle)^2\)? | No — these are generally different quantities; the average of a squared quantity is not necessarily the square of the average. |
| 14 | What does Gay Lussac's law state? | When gases combine chemically to yield another gas, their volumes are in the ratios of small integers. |
| 15 | For a vibrating diatomic gas, what are \(C_p\) and \(\gamma\)? | \( C_p = \dfrac{9}{2}R \), \( \gamma = \dfrac{9}{7} \). |
| 16 | In a PV/T vs P plot for a real gas at two temperatures (Exercise 12.3), what does the dotted line represent, and what is the value of PV/T where both curves meet the y-axis? | The dotted line represents ideal gas behaviour (PV/T independent of P). Both curves meet the y-axis (P→0) at the same value, \(\mu R\), since this depends only on the amount of gas, not its temperature or identity. |
| 17 | For the same nitrogen gas, how does the time between successive collisions compare to the duration of an individual collision (molecule size / speed)? | The time between collisions (≈\(2.2\times10^{-10}\) s) is about 500-550 times longer than the collision's own duration (≈\(4\times10^{-13}\) s) — confirming that molecules spend almost all their time moving freely, not colliding. |
| 18 | For a polyatomic gas with f vibrational modes, express f in terms of \(\gamma=C_p/C_v\). | \( f = \dfrac{4-3\gamma}{\gamma-1} \), rearranging \(\gamma=(4+f)/(3+f)\). (NEET 2024) |
| 19 | A gas has rms speed 200 m/s at 27°C (300 K). What is its rms speed at 127°C (400 K)? | \(400/\sqrt3\approx231\) m/s, from \(v_{rms}\propto\sqrt{T}\): \(v_2=200\sqrt{400/300}\) — independent of any pressure change. (NEET 2016) |